Cerium(IV) perchlorate
Cerium ion 4 Perchlorate ion.svg
Names
IUPAC name
Cerium(IV) perchlorate
Other names
  • Cerium perchlorate
  • Cerium(4+) perchlorate
  • Cerium tetraperchlorate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.794
EC Number
  • 238-290-8
  • InChI=1S/Ce.4ClHO4/c;4*2-1(3,4)5/h;4*(H,2,3,4,5)/q+4;;;;/p-4
    Key: VDNBDUGCNUZGGR-UHFFFAOYSA-J
  • [O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Ce+4]
Properties
Ce(ClO4)4
Molar mass 537.92 g/mol
Density 1.556 g/cm−3 (25 °C)[1]
Melting point 725 °C (1,337 °F; 998 K)
Hazards
GHS labelling:[2]
GHS03: Oxidizing
Warning
H272
P210, P220, P280, P370+P378, P501
Related compounds
Other cations
 Titanium perchlorate, Zirconium perchlorate
Related compounds
 Cerium(III) perchlorate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Cerium(IV) perchlorate is an inorganic compound composed of cerium and perchloric acid. It has the chemical formula of Ce(ClO4)4.

Uses

Cerium(IV) perchlorate is used as a catalyst in organic chemistry for the determination of strontium and for cerimetry.[3][4][5][6] It has a very high redox potential at Ce4+/Ce3+ of +1.87 V in 8 M HClO4.[7]

References

  1. ↑ Sigma-Aldrich Co., product no. {{{id}}}.
  2. ↑ "Cerium(4+) perchlorate". pubchem.ncbi.nlm.nih.gov.
  3. ↑ Philip L. Fuchs, André B. Charette, Tomislav Rovis, Jeffrey W. Bode (2016), Essential Reagents for Organic Synthesis (in German), John Wiley & Sons, p. 80, ISBN 978-1-119-27983-9{{citation}}: CS1 maint: multiple names: authors list (link)
  4. ↑ W.J. Mijs, C.R.H.I. de Jonge (2013), Organic Syntheses by Oxidation with Metal Compounds (in German), Springer Science & Business Media, p. 601, ISBN 978-1-4613-2109-5
  5. ↑ E. Gagliardi, E. Wolf: Bestimmung von Strontium mit Cer(IV)-perchlorat. In: Microchimica Acta. 51, 1963, S. 578, doi:10.1007/BF01217587.
  6. ↑ P. H. List, L. Hörhammer (2013), Allgemeiner Teil. Wirkstoffgruppen I (in German), Springer-Verlag, p. 301, ISBN 978-3-642-47985-4
  7. ↑ K.A. Gschneidner, Jr., J.-C.G. Bünzli and V.K. Pecharsky (2006), Handbook on the Physics and Chemistry of Rare Earths (in German), Elsevier, p. 306, ISBN 978-0-08-046672-9{{citation}}: CS1 maint: multiple names: authors list (link)


This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.